Biphasic aerobic oxidation of alcohols catalyzed by poly(ethylene glycol)-stabilized palladium nanoparticles in supercritical carbon dioxide.
نویسندگان
چکیده
منابع مشابه
Pd@[nBu₄][Br] as a Simple Catalytic System for N-Alkylation Reactions with Alcohols.
Palladium nanoparticles, simply and briefly generated in commercial and cheap onium salts using supercritical carbon dioxide, have been found to be an effective catalytic system for additive free N-alkylation reaction using alcohols via cascade oxidation/condensation/reduction steps.
متن کاملSelective aerobic oxidation in supercritical carbon dioxide catalyzed by the H5PV2Mo10O40 polyoxometalate.
Selective aerobic oxidation of benzylic alcohols and of activated aromatic hydrocarbons occurs in supercritical CO2 as reaction medium using H5PV2Mo10O40 as a quasi-heterogeneous catalyst without further additives or co-solvents; efficient recycling is possible and no metal leaching is detectable in the product stream.
متن کاملDesign of Highly Uniform Platinum and Palladium Nanoparticle Decoration on TiO2 Nanotube Arrays: An Efficient Anode to the Electro-Oxidation of Alcohols
We explore electro-catalytic properties of a system consisting of platinum and palladium nanoparticles dispersed over a nanotubular self-organized TiO2 matrix. These electrodes prepared by electroess and microemulsion of palladium and palladium nanoparticles on to TiO2 nanotubes, respectively. Titanium oxide nanotubes were fabricated by anodizing titanium foil in ethylene glycol (EG) fluoride-c...
متن کاملSustained release of nucleic acids from polymeric nanoparticles using microemulsion precipitation in supercritical carbon dioxide.
A general approach for producing biodegradable nanoparticles for sustained nucleic acid release is presented. The nanoparticles are produced by precipitating a water-in-oil microemulsion in supercritical CO(2). The microemulsion consists of a transfer RNA aqueous solution (water phase), dichloromethane containing poly(l-lactic acid)-poly(ethylene glycol) (oil phase), the surfactant n-octyl β-D-...
متن کاملHomogeneous Catalysis and Catalyst Recovery Using Supercritical Carbon Dioxide and Ionic Liquids
The combination of scCO2 with a non-volatile liquid such as ionic liquids, water, or poly(ethylene glycol) creates a biphasic mixture suitable for homogeneous catalysis with facile catalyst/product separation and catalyst recycling. Continuous-flow processes are also possible. Dissolution of the CO2 into the nonvolatile liquid during the reaction can have desirable or undesirable effects on the...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Angewandte Chemie
دوره 44 9 شماره
صفحات -
تاریخ انتشار 2005